Research
My
research interests are in using experiments combined with applied
mathematics to solve energy and pollution problems.
Polymer
Composites for Fuel Cell Bipolar Plates
Fuel Cells have been proposed as an alternative to fossil fuels
for stationary and transportation applications. In order to make
this a possibility, several fundamental changes must occur. One
particular area is the development of a new bipolar plate material.
These plates separate one cell from another within the fuel cell,
and have channels etched to allow for reactant and product flows.
These plates are currently made from the addition of a graphite
powder to a thermosetting polymer. This polymer cannot be remelted
and reused in bipolar plate applications.
In this project we are investigating a more sustainable way to
develop the bipolar plate material. This involves the use of a liquid
crystal polymer. Furthermore, we are attempting to improve the thermal
and electrical conductivities of the fuel cell bipolar plate through
the addition of multiple carbon fillers (carbon black, synthetic
graphite, and carbon fiber) which has been shown to have a synergistic
effect on these important material properties.
After extruding the polymer and filler into pellets, they are injection
molded into samples, which are tested for thermal conductivity,
electrical conductivity, and tensile strength. The rheology is tested
on the extruded pellets.
Chemical
Reactor Dynamics
Tight emissions standards are being developed for diesel fueled
vehicles. We are using thermal stability theory to understand the
ignition phenomenon within design diesel particulate traps to reduce
emission of these harmful particles.
Selected
Publications
J. M. Keith, J. A. King, R. L. Barton, “Electrical Conductivity Modeling of Carbon-Filled Liquid Crystal Polymer Composites,” Journal of Applied Polymer Science, 102, 3293-3300 (2006).
J. M. Keith, C. D. Hingst, M. G. Miller, J. A. King, and R. A. Hauser,
“Measuring and Predicting In-Plane Thermal Conductivity of Carbon-Filled
Nylon 6,6 Polymer Composites,” Polymer Composites, 27, 1-7 (2006)
J.
A. King, M. G. Miller, R.L. Barton, J. M. Keith, R. A. Hauser, K.
Peterson, and L. L. Sutter, “Thermal and Electrical Conductivity
of Carbon-Filled Liquid Crystal Polymer Composites,” Journal of
Applied Polymer Science, 99, 1552-1558 (2006).
H.
Zheng and J. M. Keith (by invitation), “Thermal Stability of Chemical
Reactors,” Encyclopedia of Chemical Processing, Sunggyu Lee, editor;
vol. 4, pp. 2997-3008 (2005).
F.
L. Chan and J. M. Keith, “Designing Reverse Flow Packed Bed Reactors
for Stable Treatment of Volatile Organic Compounds,” Journal of
Environmental Management, 78, 223-231 (2006).
H. Zheng and J. M. Keith, “Ignition Analysis of Wall-Flow Monolith Diesel Particulate Filters,” Catalysis Today, 98, 403-412 (2004).
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